like others have said, you probably won't see much (if any) difference now. if it's ddr2 or 3, it may well be worth getting anyway, since you'ld probably be able to use it in your next system. i think johntp hit it; it's good for future-proofing.
here is an article from corsair that examines 2 gb vs 4 gb. there are some gains, but it's coming from a memory company so i'd take it with a grain or two of salt.